4,5-Diiodo-2-phenyl-1H-imidazole

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4,5-Diiodo-2-phenyl-1H-imidazole

The structure of the title compound, C(9)H(6)I(2)N(2), contains two symmetry-independent mol-ecules. The inter-planar angles between the imidazole and phenyl ring planes are 16.35 (3) and 17.48 (6)°. Mol-ecules are connected via N-H⋯N hydrogen bonds to form zigzag chains along the b axis. The title compound is the first example of a structurally characterized 4,5-diiodo-imidazole with an organi...

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2-Phenyl-1H-imidazole

In the title compound, C(9)H(8)N(2), a mirror plane lies perpendicular to the phenyl and imidazole rings and passes through the bridging C-C bond, so that the imidazole ring is disordered over two sites about the mirror plane with the equal site occupancy; the asymmetric unit contains one half-mol-ecule. In the crystal, adjacent mol-ecules are linked via N-H⋯N hydrogen bonds.

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4-Phenyl-1H-imidazole-2(3H)-thione

In the asymmetric unit of the title compound, C(9)H(8)N(2)S, there are four symmetry-independent mol-ecules (Z' = 4). The geometrical features of these mol-ecules are quite similar: in the normal probability plots the R(2) correlation factors for bond lengths and angles are generally around 0.95. The twist angles between the imidazole and phenyl rings (which are planar within 3σ) range from 9.0...

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2-Phenyl-4,5-di-2-pyridyl-1H-imidazole

In the title compound, C(19)H(14)N(4), which was crystallized from dimethyl sulfoxide, the arene and heterocyclic rings of the lophine analogue framework differ only slightly from coplanarity (dihedral angles range from 8.8 to 20.2°), and intramolecular N-H⋯N and C-H⋯N interactions help to establish the conformation. The crystal packing features a number of weak C-H⋯N, N-H⋯N hydrogen-bond type ...

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4,5-Dimethyl-2-phenyl-1-(p-tol­yl)-1H-imidazole

In the title compound, C(18)H(18)N(2), the imidazole ring is essentially planar [maximum deviation = 0.004 (1) Å] and makes dihedral angles of 68.91 (8) and 20.43 (9)° with the tolyl and phenyl rings, respectively. The dihedral angle between the latter rings is 73.62 (8)°. The crystal packing is stabilized by inter-molecular C-H⋯N hydrogen bonds.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2012

ISSN: 1600-5368

DOI: 10.1107/s1600536812003017